Polymer TestingL04 · Impact Testing: Izod vs Charpy Pendulum Dynamics & Fracture Mechanics
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Testing & QA/QCLesson 0419 PPE Syllabus Aligned

Impact Testing: Izod vs Charpy Pendulum Dynamics & Fracture Mechanics

Understand how impact resistance — a property tensile testing cannot measure — is quantified using Izod and Charpy pendulum tests, and why this single property often determines real-world product failure.

~35 min technical deep-dive·Standard Indian Curricula (CIPET / Anna Univ / ICT)

01 · Why This Matters in Industry & GATE XE5

Applied directly across petrochemical refining, compounding plants, mold-flow simulations, and automotive part manufacturing (e.g., Reliance Industries, Supreme Petrochem, IOCL, CIPET testing protocols).

1

Molecular Mechanism: Master conformational physics, transition temperatures, and reaction kinetics.

2

Process & Quality: Predict viscosity behavior, solve moulding defects, and apply ASTM/ISO testing standards.

02 · Technical Theory & Governing Equations

Impact Testing: Izod vs Charpy Pendulum Dynamics & Fracture Mechanics

1. Why This Topic Matters

Polymer components subjected to sudden mechanical impacts (drop impact, collision, shock loading) must resist brittle fracture. Pendulum Impact Testing—via Izod and Charpy methods—measures the energy absorbed during rapid crack propagation across a standardized notched specimen. Understanding notch sensitivity, ductile-to-brittle transition temperature (DBTTDBTT), and the non-interchangeable differences between ASTM and ISO test standards is critical for automotive bumper and protective helmet material selection.

2. Learning Objectives

By completing this lesson, you will be able to:

  • Differentiate Izod (cantilever beam) and Charpy (three-point supported beam) testing geometries.
  • Calculate absorbed impact energy (EabsorbedE_{absorbed}) and impact strength.
  • Compare ASTM D256 (extJ/m ext{J/m}) and ISO 180 / ISO 179 (extkJ/m2 ext{kJ/m}^2) units and notch radii.
  • Diagnose notch sensitivity and brittle failure modes.

3. Test Geometry & Pendulum Dynamics

Technical Schematic & Mechanism Blueprint: Impact Testing: Izod vs Charpy Pendulum Dynamics & Fracture Mechanics
Technical Schematic & Mechanism Blueprint: Impact Testing: Izod vs Charpy Pendulum Dynamics & Fracture Mechanics

Impact Testing: Izod vs Charpy Pendulum Dynamics & Fracture Mechanics — Mechanism & Physics Diagram
RETENTION VOLUME / ELUTION TIME → (LOW MW ELUTES LATER)DETECTOR RESPONSE (dRI / UV)Calibration: log(M) = -A·Vr + BMzMwMnPDI (Polydispersity):Mw / Mn ≥ 1.00
Analytical SEC Chromatography: Larger hydrodynamic volumes are excluded from porous gel pores and elute first; Mz > Mw > Mn for all polydisperse polymers.
mermaid
graph TD A["Pendulum Released from Initial Height h1"] --> B["Impact Striker Strikes Notched Specimen"] B --> C{"Testing Configuration"} C -->|"Izod Method (ASTM D256 / ISO 180)"| D["Vertical Cantilever Beam (Struck on Notched Face Side)"] C -->|"Charpy Method (ISO 179)"| E["Horizontal Simply Supported Beam (Struck Opposite Notch)"] D --> F["Pendulum Swings to Reduced Height h2"] E --> F F --> G["Absorbed Energy E = m*g*(h1 - h2) - Friction Losses"]

4. Equations & Recalculated Impact Energy

Impact Testing: Izod vs Charpy Pendulum Dynamics & Fracture Mechanics — Industrial Process Flow Diagram (PFD)

ISO 10628 Unit Operations & Thermodynamic Control Sequence

ISO 10628 PFD Standard
180°C - 100°C
Raw Material Feed & Metering

Drying to < 0.02% moisture and gravimetric dosing

Output:Conditioned Feed
2220°C - 260°C
Reaction & Polymer Melt Processing

Controlled thermal shear dissipation and phase transition

Output:Homogenous Melt
360 - 120 bar
Shaping & Solidification

Die extrusion or mold cavity pressure packing

Output:Formed Component
4QA Passed
Quality Inspection & Testing

ASTM D638 / ISO 527 tensile & MFI compliance check

Output:Finished Grade
Recycle Loop Stream:Closed-loop sprues and edge-trim regrind re-fed into main hopper at maximum 15% blend ratio.
Standard Indian Industrial Practice (CIPET / Reliance / Supreme Petrochem Protocol)

Pendulum Energy Equation

Potential energy absorbed by specimen fracture:

Eabsorbed=m⋅g⋅(h1−h2)−EwindageE_{absorbed} = m \cdot g \cdot (h_1 - h_2) - E_{windage}

Unit Formats: ASTM vs ISO Standards

Engineering Note & Problem Analysis

[!CAUTION] Never Interchange ASTM and ISO Impact Values:

  • ASTM D256 (Izod) reports impact energy per unit notch length (extJ/m ext{J/m}):
Impact StrengthASTM=Eabsorbedb(J/m)\text{Impact Strength}_{ASTM} = \frac{E_{absorbed}}{b} \quad (\text{J/m})
Engineering Note & Problem Analysis
  • ISO 180 (Izod) / ISO 179 (Charpy) reports impact energy per unit cross-sectional area under notch (extkJ/m2 ext{kJ/m}^2):
Impact StrengthISO=Eabsorbedb⋅(h−a)×103(kJ/m2)\text{Impact Strength}_{ISO} = \frac{E_{absorbed}}{b \cdot (h - a)} \times 10^3 \quad (\text{kJ/m}^2)

Where bb = specimen width (0.0032extm0.0032 ext{ m}), hh = total thickness (0.0127extm0.0127 ext{ m}), aa = notch depth (0.00254extm0.00254 ext{ m}).

Worked Numerical Example:

Engineering Note & Problem Analysis

Problem Statement:

Problem: A Polycarbonate notched Izod specimen (b=3.20 mm=0.0032 mb = 3.20\text{ mm} = 0.0032\text{ m}, depth under notch h−a=10.16 mm=0.01016 mh - a = 10.16\text{ mm} = 0.01016\text{ m}) absorbs Eabsorbed=2.10 JoulesE_{absorbed} = 2.10\text{ Joules} during fracture. Calculate impact strength under both ASTM D256 and ISO 180 formats.

Engineering Note & Problem Analysis

Solution Step:

Solution:

  1. Calculate ASTM D256 Impact Strength (extJ/m ext{J/m}):
Impact StrengthASTM=2.10 J0.00320 m=656.25 J/m\text{Impact Strength}_{ASTM} = \frac{2.10\text{ J}}{0.00320\text{ m}} = 656.25\text{ J/m}
  1. Calculate ISO 180 Impact Strength (extkJ/m2 ext{kJ/m}^2):
Cross-Section Area=0.00320×0.01016=3.2512×10−5 m2\text{Cross-Section Area} = 0.00320 \times 0.01016 = 3.2512 \times 10^{-5}\text{ m}^2 Impact StrengthISO=2.10 J3.2512×10−5 m2=64,591.5 J/m2=64.59 kJ/m2\text{Impact Strength}_{ISO} = \frac{2.10\text{ J}}{3.2512 \times 10^{-5}\text{ m}^2} = 64,591.5\text{ J/m}^2 = 64.59\text{ kJ/m}^2

5. Industrial Applications

Impact Testing: Izod vs Charpy Pendulum Dynamics & Fracture Mechanics — CAD Tooling & Machine Geometry Blueprint

DWG NO: DWG-POLY-2026-232SCALE: 1:1 (FULL)MATERIAL: P20 Tool Steel / Hardened Alloy (HRC 48-52)
CL MOULD MOUNTINGCAVITY 1CAVITY 2SPRUE BUSHING (Ø6.5mm)WATER INLET (Ø10mm)160.00 ± 0.02 mm
Critical Geometric Dimensions & Tolerances (GD&T)
  • Primary Processing Tolerance:± 0.02 mm (ISO 20457 Class M1)
  • Thermal Expansion Allowance:1.5% (Volumetric Shrinkage)
  • Draft Angle Minimum:1.0° - 1.5° (Core/Cavity Ejection)
Tooling Fabrication Notes
  • • Fabricated according to ISO 20457 plastic molding tolerance standards.
  • • EDM finish SPI C-1 applied across cavity optical contact faces.
  • • Conformal cooling lines pressure tested at 12 bar water flow.
  • Automotive Bumper Compound Validation: Polypropylene-EPDM tough impact testing at −30circextC-30^circ ext{C} in Chennai auto testing lab. (Illustrative Indian industry scenario based on automotive polymer testing).

6. Key Takeaways & Glossary

  • Notch Sensitivity: Susceptibility of material to brittle fracture caused by stress concentration at sharp notch roots (R=0.25extmmR = 0.25 ext{ mm}).
  • DBTT: Ductile-to-Brittle Transition Temperature where impact strength drops sharply.

7. Sources & Standard References

  1. ASTM D256-23 — Standard Test Methods for Determining the Izod Pendulum Impact Resistance of Plastics, ASTM.
  2. ISO 179-1:2023 — Plastics — Determination of Charpy impact properties, ISO.

Impact Testing: Izod vs Charpy Pendulum Dynamics & Fracture Mechanics · Engineering Triad

Material Synthesis · Processing Hardware · Commercial Application

ASTM / ISO Aligned
1. MaterialResin / Chemistry

Acrylonitrile Butadiene Styrene (ABS)

Poly(acrylonitrile-co-butadiene-co-styrene) Terpolymer

Izod Impact (Notched):180–300 J/m
Heat Deflection (0.45MPa):92–98 °C
Tensile Yield Strength:42–50 MPa
Rockwell Hardness:R 105–112
Morphology: SAN Matrix with dispersed Polybutadiene rubber graft spheres
2. Machine & MouldShop Floor

Computerized Servo-Universal Testing Machine (UTM 50kN)

Dual-Column Testing Rig with Video Extensometer

Crosshead Speed:50 mm/min (ASTM D638)
Gauge Length:50.0 ± 0.1 mm
Load Cell Precision:Class 0.5 (±0.5% accuracy)
Temperature Chamber:23.0 ± 2.0 °C / 50% RH
Tooling: Pneumatic Wedge Action Grips with Diamond-Serrated Jaw Faces
3. Real ProductApplication

Consumer Electronics Enclosures & Crash Helmets

Dimensional stability & high impact absorbing protective shells

Standard:ASTM D638 / ASTM D256 / ISO 178 / IS 4151
Resin Grades: LG Chem ABS AF312, INEOS Styrolution Terluran GP-22
Section 05 · Knowledge Check

Test Your Conceptual Understanding

In polymer science and processing thermodynamics, which factor most directly controls the critical transition temperature?

Select the correct option to verifyTake Complete Topic Assessment →
Summary Cheat Sheet & GATE Takeaways
  • Always evaluate molecular weight distribution (MWD) alongside zero-shear viscosity when calculating mold shear rates.
  • Differential Scanning Calorimetry (DSC) provides $T_g$, $T_c$, and $T_m$ to define optimal processing temperatures.
  • Comply with ASTM D638 / ISO 527 tensile specimen sizing to prevent premature necking artifacts.
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